Already in the early 2000s, companies producing and placing on the market hair colouring products decided to collaborate on the generation and preparation of safety data and information needed to address regulatory requests and/or to comply with obligations pertaining to hair colouring ingredients and/or finished cosmetic hair colouring product use. The companies formed the Hair Colouring Product Safety (HCPS) Consortium.
Initially, the HCPS Consortium undertook to generate information regarding a number of hair dyes, so called Common Interest Dyes (CIDs), under the EU hair dye strategy1. This work was mostly completed some years ago, but recent regulatory developments related to both human as well as environmental safety make it necessary to conduct further work to support continued use of hair dyes in cosmetic products.
A review of the use and interest of the Consortium members led to changes in the list of dyes that are considered CIDs by the consortium.
1Docsroom - European Commission
The current new list of CIDs is as follows:
|
Common Interest Hair Dye ingredients (CIDs) |
||
|
Colipa code |
INCI |
CAS |
1 |
A005 |
Toluene-2,5-diamine; Toluene-2,5-Diamine Sulfate |
95-70-5; 615-50-9 |
2 |
A007 |
p-Phenylene-diamine; p-Phenylene-diamine HCl; p-Phenylene-diamine Sulphate |
106-50-3; 624-18-0; 16245-77-5 |
3 |
A011 |
Resorcinol |
108-46-3 |
4 |
A012 |
4-Chlororesorcinol |
95-88-5 |
5 |
A015 |
m-Aminophenol; m-Aminophenol HCl; m-Aminophenol sulfate |
591-27-5; |
6 |
A016 |
p-Aminophenol |
123-30-8 |
7 |
A017 |
1-Naphthol |
90-15-3 |
8 |
A018 |
1,5-Naphthalenediol |
83-56-7 |
9 |
A019 |
2,7-Naphthalenediol |
582-17-2 |
10 |
A022 |
p-Methyl aminophenol; p-Methyl aminophenol sulphate |
150-75-4; 55-55-0; 1936-57-8 |
11 |
A027 |
4-Amino-2-hydroxytoluene |
2835-95-2 |
12 |
A031 |
2-Methyl-5-hydroxyethylaminophenol |
55302-96-0 |
13 |
A039 |
Phenyl methyl pyrazalone |
89-25-8 |
14 |
A042 |
2,4-Diaminophenoxyethanol HCl; 2,4-Diaminophenoxyethanol sulfate |
70643-19-5; 66422-95-5; 70643-20-8 |
15 |
A044 |
2-Methylresorcinol |
608-25-3 |
16 |
A050 |
N,N-bis(2-Hydroxyethyl)-p-phenylene diamine sulfate |
54381-16-7 |
17 |
A074 |
4-Amino-m-cresol |
2835-99-6 |
18 |
A079 |
1,3-bis-(2,4- Diaminophenoxy) propane; 1,3-Bis-(2,4-diaminophenoxy)-propane HCl |
81892-72-0; 74918-21-1 |
19 |
A080 |
Hydroxyethyl-p-phenylenediamine sulphate |
93841-25-9 |
20 |
A084 |
2-Amino-4-hydroxyethylaminoanisole; 2-Amino-4- Hydroxyethylaminoanisole sulfate |
83763-47-7; 83763-48-8 |
21 |
A094 |
5-Amino-6-chloro-o-cresol; 5-Amino-6- Chloro-o-Cresol HCl |
84540-50-1; 80419-48-3 |
22 |
A098 |
Hydroxyethyl-3,4-methylenedioxyaniline HCl |
94158-14-2 |
23 |
A099 |
2,6-Dihydroxy-3,4-dimethylpyridine |
84540-47-6 |
24 |
A111 |
Dihydroxyindole |
3131-52-0 |
25 |
A130 |
6-Methoxy-2-methylamino-3-aminopyridine HCl |
83732-72-3; 90817-34-8 |
26 |
A132 |
2-Amino-3-hydroxypyridine |
16867-03-1 |
27 |
A136 |
2,6-Diaminopyridine |
141-86-6 |
28 |
A147 |
Dihydroxy indoline; Dihydroxyindoline HBr |
29539-03-5; 138937-28-7 |
29 |
A154 |
1-Hydroxyethyl-4,5-diaminopyrazole sulfate |
155601-30-2 |
30 |
A160 |
2-Methoxymethyl-p-Phenylenediamine; 2-Methoxymethyl-p-Phenylenediamine Sulfate |
337906-36-2; 337906-37-3 |
31 |
B007 |
Basic Brown 17 |
68391-32-2 |
32 |
B015 |
Acid Black 1 |
1064-48-8 |
33 |
B024 |
4-Nitro-o-phenylenediamine |
99-56-9 |
34 |
B028 |
Picramic Acid; Sodium Picramat |
96-91-3 831-52-7 |
35 |
B034 |
N,N’-bis(Hydroxyethyl)-2-nitro-p- phenylenediamine |
84041-77-0 |
36 |
B037 |
HC Blue n°2 |
33229-34-4 |
37 |
B038 |
HC Yellow n°4 |
59820-43-8 |
38 |
B041 |
HC Yellow n°2 |
4926-55-0 |
39 |
B050 |
HC Red n°3 |
2871-01-4 |
40 |
B051 |
4-Amino-3-nitrophenol |
610-81-1 |
41 |
B054 |
3-Nitro-p-hydroxyethylaminophenol |
65235-31-6 |
42 |
B073 |
HC Blue n°12 |
104516-93-0; 132885-85-9 (HCl) |
43 |
B075 |
Hydroxyethyl-2-nitro-p-toluidine |
100418-33-5 |
44 |
B098 |
HC Violet n°2 |
104226-19-9 |
45 |
B099 |
2-Amino-6-chloro-4-nitrophenol |
6358-09-4 |
46 |
B100 |
4-Hydroxypropylamino-3- nitrophenol |
92952-81-3 |
47 |
B115 |
Basic Violet 2 |
3248-91-7 |
48 |
B116 |
Basic Red 51 |
77061-58-6 |
49 |
B117 |
Basic Yellow 87 |
68259-00-7 |
50 |
B118 |
Basic Orange 31 |
97404-02-9 |
51 |
B119 |
HC Blue n° 16 |
502453-61-4 |
52 |
B122 |
HC Blue 18 |
1166834-57-6 |
53 |
B123 |
HC Yellow n°16 |
1184721-10-5 |
54 |
B124 |
HC Red n°18 |
1444596-49-9 |
55 |
C008 |
Basic Red 76 |
68391-30-0 |
56 |
C010 |
Basic Yellow 57 |
68391-31-1 |
57 |
C015 |
Acid Orange 7 |
633-96-5 |
58 |
C022 |
Acid Red 33 |
3567-66-6 |
59 |
C029 |
Acid Yellow 23; Acid Yellow 23 Aluminum lake |
1934-21-0; 12225-21-7 |
60 |
C040 |
Acid Blue 9; Acid Blue 9 Ammonium Salt; Acid Blue 9 Aluminum Lake |
3844-45-9; 2650-18-2; 68921-42-6 |
61 |
C053 |
Acid Red 92 |
18472-87-2 |
62 |
C054 |
Acid Yellow 3 |
8004-92-0 |
63 |
C063 |
Acid Violet 43 |
4430-18-6 |
64 |
C064 |
Disperse Violet 1 |
128-95-0 |
65 |
C106 |
Disperse Black 9 |
20721-50-0 |
66 |
C169 |
Lawsonia inermis (Henna) |
84988-66-9 |
67 |
C170 |
Indigofera tinctoria |
84775-63-3 |
68 |
C175 |
Acid Red 18; Acid Red 18 Aluminum Lake |
2611-82-7; 12227-64-4 |
69 |
C177 |
Acid Red 52 |
3520-42-1 |
70 |
C178 |
Acid Green 25 |
4403-90-1 |
71 |
C182 |
HC Blue n°15 |
74578-10-2 |
72 |
C183 |
Tetrabromophenol Blue |
4430-25-5 |
73 |
C184 |
HC Blue n°17 (arianor blue 347) |
16517-75-2 |
NB: It is important to note that this list is tentative and constitutes a starting point for a vulnerability analysis. This means that not all these dyes might be part of the final list of dyes that the Consortium will work on. The HCPS consortium will inform again as soon as the final list of CIDs is established.
For questions, please contact Torben Koenig at Cosmetics Europe.